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Beilstein J. Org. Chem. 2007, 3, No. 32, doi:10.1186/1860-5397-3-32
Graphical Abstract
Scheme 1: Allylsilane-N-acyliminium cyclisation.
Scheme 2: Enantioselective synthesis of (-)-indolizidine 167B by intramolecular allylsilane-N-acyliminium cyc...
Scheme 3: Synthesis of (±)-indolizidine 167B by intermolecular cyclisation of allylsilane-N-acyliminium cycli...
Scheme 4: Synthesis of 3,5-disubstituted indolizidines from L-pyroglutamic acid.
Scheme 5: Access to indolizidine precursors of dendroprimine starting from chiral 2-aminopropanoate.
Scheme 6: Access to (-)-dendroprimine by reduction with LiAlH4 of indolizidinones 26.
Scheme 7: Access to (-)-dendroprimine by catalytic hydrogenation of indolizidinones 26.
Scheme 8: Synthesis of (±)-myrtine and (±)-epimyrtine.
Scheme 9: Enantioselective synthesis of (+)-myrtine and (-)-epimyrtine.
Scheme 10: Synthesis of (±)-lasubines I and II and (±)-2-epilasubine II.
Scheme 11: Synthesis of (±)-lasubine I and II.
Scheme 12: Enantioselective synthesis of (-)-lasubines I and II and (+)-subcosine.